The growing demand for grid-scale energy storage calls for safe and low-cost solutions, for which zinc-iodine flow batteries (ZIFBs) are highly promising. However, their practical application is critically hindered by two issues: accumulation of insoluble solid iodine at the cathode and zinc dendrite growth at the anode.
Aqueous zinc-iodine flow batteries show potential in large-scale storage but face water imbalance-induced instability. Here, authors develop a tailored ionic-molecular sieve membrane that selectively intercepts hydrated ions, enabling stable high-capacity long cycling with low projected costs.
Nevertheless, the development of aqueous zinc-iodine batteries has been impeded by persistent challenges associated with iodine cathodes and Zn anodes. Key obstacles include the shuttle effect of polyiodine and the sluggish kinetics of cathodes, dendrite formation, the hydrogen evolution reaction (HER), and the corrosion and passivation of anodes.
Zinc-iodine batteries are emerging as a promising candidate for large-scale energy storage due to their intrinsic safety, low cost, and environmental friendliness. Compared with lithium-ion batteries, aqueous zinc-based systems offer considerable advantages in terms of resource abundance and thermal stability.
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Consuming one-third of iodide to stabilize the iodine for reversible I−/I3− reactions is the major challenge for zinc–iodine flow batteries (ZIFBs) to …
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Nevertheless, the development of aqueous zinc-iodine batteries has been impeded by persistent challenges associated with iodine cathodes and Zn anodes. Key …
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Applying this strategy, we demonstrate a novel zinc/iodine–bromide battery to achieve an energy density of 101 W h L …
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Researchers reported a 1.6 V dendrite-free zinc-iodine flow battery using a chelated Zn(PPi)26- negolyte. The battery demonstrated stable operation at 200 mA cm−2 over 250 …
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Inspired by the significant chromogenic reaction between starch and iodine, the shuttle effect of Zn–I2 batteries is effectively addressed by using …
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Aqueous zinc-iodine batteries stand out as highly promising energy storage systems owing to the abundance of resources and non …
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Aqueous zinc-iodine flow batteries show potential in large-scale storage but face water imbalance-induced instability. Here, authors develop a tailored ionic-molecular sieve …
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This review provides an in-depth understanding of all theoretical reaction mechanisms to date concerning zinc–iodine batteries. It revisits the inherent issues and …
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The optimization of electrolyte is of great significance for achieving high-performance aqueous zinc-iodine batteries. This review …
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Researchers reported a 1.6 V dendrite-free zinc-iodine flow battery using a chelated Zn(PPi)26- negolyte. The battery demonstrated …
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Aqueous rechargeable zinc–iodine batteries are emerging high-safety and cost-effective technology for large-scale energy storage. …
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Abstract Zinc–iodine batteries (ZIBs) are promising candidates for safe and sustainable energy storage but are hindered by polyiodide shuttling, leading to rapid capacity …
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The growing demand for grid-scale energy storage calls for safe and low-cost solutions, for which zinc-iodine flow batteries (ZIFBs) are highly promising. However, their practical application is …
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Zinc–iodine batteries are one of the most intriguing types of batteries that offer high energy density and low toxicity. However, the low …
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However, the development of zinc‑iodine flow batteries still suffers from low iodide availability, iodide shuttling effect, and zinc dendrites.
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Therefore, it can be foreseen that further optimization of the colloidal chemistry-based flow battery components can advance a new arena of next-generation zinc-based flow …
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The "SpaceFlow"battery is realized as a zinc-polyiodide hybrid flow battery, which achieved incomparably high energy densities in laboratory tests. An energy density of 167 …
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This review provides an in-depth understanding of all theoretical reaction mechanisms to date concerning zinc–iodine batteries. …
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Context & scale Zinc-iodine batteries are emerging as a promising candidate for large-scale energy storage due to their intrinsic safety, low cost, and environmental …
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The zinc‑chlorine and zinc‑bromine RFBs were demonstrated in 1921, and 1977, respectively, and the zinc‑iodine RFB was proposed by Li et al. in 2015 . What is a highly stable zinc iodine …
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In this perspective, we attempt to provide a comprehensive overview of battery components, cell stacks, and demonstration systems for zinc-based flow batteries. We begin …
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Abstract Zinc–iodine batteries (ZIBs) are promising candidates for safe and sustainable energy storage but are hindered by …
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BESSt announced that its new redox flow battery technology delivers 20 times the energy density of conventional vanadium flow storage systems. The battery is based on a …
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What is a zinc-polyiodide flow battery? A zinc-polyiodide flow battery is a promising candidate for various energy storage applications. It stands out due to its high-energy density and benign …
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